I think the cold air comes on fairly quick in my F80 but since the passenger area is fairly large greenhouse it takes some time on Full A/C to cool the car completely. I find that if I open all the windows first, full A/C and drive off, then close the windows it helps on really hot days.
I've also installed the BMW Remote app and start the A/C a few minutes before heading out to the car when I can. It's awesome (if you have that option).
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